MP-AES consists of a microwave induced plasma
interfaced to an atomic emission spectrophotometer (AES). It is used for simultaneous multi-analyte
determination of major and minor elements. MPAES employs microwave energy to
produce a plasma discharge using nitrogen supplied from a gas cylinder or
extracted from ambient air, which eliminates the need for sourcing gases in
remote locations or foreign countries. Samples are typically nebulized prior to
interaction with the plasma in MP-AES measurements. The atomized sample passes through the plasma
and electrons are promoted to the excited state. The light emitted electrons return to the
ground state light is separated into a spectrum and the intensity of each
emission line measured at the detector. Most commonly determined elements can
be measured with a working range of low part per million (ppm) to weight
percent (wt. %). MP-AES is a technique comparable to traditional AA and AES
but with several potential advantages including lower cost of operation and
elimination of the requirement for flammable gasses. MP-AES instruments are benchtop
instruments. While the technique is
mature, there are a limited number of manufacturers supplying commercial MP-AES
instruments.