ICP-OES consists of an
inductively coupled plasma (ICP) interfaced to an optical emission
spectrophotometer (OES) and is used for simultaneous multi-analyte
determination of ~78 elements on the periodic table. ICP-OES utilizes a plasma gas to sequentially
desolvate, vaporize, atomize, and ionize samples for elemental analysis.. As
the ions produced move into the cooler region of the plasma they return to the
ground state by absorbing electrons, simultaneously emitting light at wavelengths
characteristic of the element. The emitted light is separated into a spectrum
and the intensity of each emission line measured at the detector. Detectors
include charge coupled devices (CCD), charge injection devices (CID), and diode
arrays. CCDs and CIDs are most common as they have wavelength coverage from the
ultraviolet (UV) to infrared (IR) region of the spectrum, and can capture full
spectral images allowing simultaneous quantitation of all detected emission.
The typical working range is low part per billion (ppb) to percent composition
(%). As with ICP-MS both solid and
liquid samples can be analyzed with this technique dependent upon the sample
introduction system. ICP-OES instruments are benchtop models. The technique is mature and a number of
instruments are commercially available.